Vorticity banding during the lamellar-to-onion transition in a lyotropic surfactant solution in shear flow.
نویسندگان
چکیده
We report on the rheology of a lyotropic lamellar surfactant solution (SDS/dodecane/pentanol/ water), and identify a discontinuous transition between two shear thinning regimes which correspond to the low-stress lamellar phase and the more viscous shear-induced multilamellar vesicle, or "onion" phase. We study in detail the flow curve, stress as a function of shear rate, during the transition region, and present evidence that the region consists of a shear-banded phase where the material has macroscopically separated into bands of lamellae and onions stacked in the vorticity direction. We infer very slow and irregular transformations from lamellae to onions as the stress is increased through the two-phase region, and identify distinct events consistent with the nucleation of small fractions of onions that coexist with sheared lamellae.
منابع مشابه
Lamellar to Onion Transitions with Increasing Temperature under Shear Flow in a Nonionic Surfactant System Studied by Rheo-SAXS
Introduction In the past 15 years, much attention has been paid to the effects of shear flow on the structure of the lyotropic phase of surfactant systems, especially on the lamellar phase. Among them, the most striking result may be the transition from the lamellar phase to the "onion phase" where all the space is filled by multilamellar vesicles alone [1]. Although this type of transition has...
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ورودعنوان ژورنال:
- The European physical journal. E, Soft matter
دوره 21 2 شماره
صفحات -
تاریخ انتشار 2006